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Abstract
Peningkatan kapasitas industri memberikan dampak positif bagi masyarakat namun meninggalkan jejak kerusakan bagi lingkungan. Tujuan penelitian ini untuk membantu menangani limbah metilen biru yang sering menjadi bahan buangan dari aktivitas industri. Metilen biru menjadi salah satu masalah karena mencemari lingkungan. Berbagai penyakit misalnya kanker maupun perubahan genetik bisa terjadi karena bioakumulasi bahan ini. Penanganan masalah pencemaran lingkungan akibat metilen biru telah banyak dilakukan misalnya menggunakan metode adsorpsi, karena metode ini cukup sederhana dan mudah diterapkan. Berbagai bahan alam digunakan sebagai adsorben, salah satu contoh limbah yang bisa dijadikan sebagai adsorben yaitu serbuk gergaji kayu jati. Serbuk gergaji kayu jati pada penelitian ini diaktivasi menggunakan larutan asam sulfat. Selanjutnya dilakukan karakterisasi menggunakan FTIR, SEM-EDX dan pHpzc. Setelah dikarakterisasi lalu dilakukan analisis adsorpsi metilen biru secara batch. Variabel penelitian yaitu variasi pH dan waktu kontak. Hasil penelitian menunjukkan bahwa adsorpsi maksimal pada pH 6 dengan kapasitas adsorpsi 1,96 mg g
-1 (99,3%) dan waktu kontak maksimum yaitu 30 menit dengan nilai Qe adalah 1,97-1mg g (99,7%).
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References
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- Riyanto, Mawazi, M., 2015. Electrochemical Degradation of Methylene Blue Using Carbon Composite Electrode (C-PVC) in Sodium Chloride. IOSR Journal of Applied Chemistry 8, 31–40. https://doi.org/10.9790/5736-081113140
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References
Aktar, M.S., Shakil, M.S.R., Tuj-Zohra, F., 2023. Potentials of bio-adsorbent prepared from coconut fibre in mitigation of pollution from tanning effluent. Cleaner Engineering and Technology. Charge (PZC) of Concrete Particles Adsorbents. IOP Conf. Ser.: Mater. Sci. Eng., 1184, 012004. Coconut Fiber Biosorbent. WJC 4, 131–138. https://doi.org/10.21580/wjc.v4i2.8941 https://doi.org/10.1088/1757899X/1184/1/012004
Baunsele, A.B., Missa, H., 2020. Kajian Kinetika Adsorpsi Metilen Biru Menggunakan Adsorben Sabut Kelapa. Akta Kimia Indonesia 5, 76. https://doi.org/10.12962/j25493736.v5i2.7791
Andarista, F.F., Huda, M.M., Dewati, R., 2023. Adsorpsi Logam Timbal Pada Limbah Cair Artifisial Menggunakan Arang Aktif Eceng Gondok. Jurnal Teknik Kimia 18, 33–39. https://doi.org/10.33005/jurnal_tekkim.v18i1.4122
Asiah, N., Sylvia, N., Bahri, S., 2022. Adsorpsi Zat Warna Methylene Blue Menggunakan Adsorben Dari Ampas Teh Pada Kolom. Chemical Eng. J. Storage 2, 75.
Baunsele, A.B., Tukan, M.B., Taek, M.M., Tukan, G.D., Kopon, A.M., Boelan, E.G., Leba, M.A.U., Komisia, F., Missa, H., Siswanta, D., Naat, J.N., Rahayu, R., 2024b. Adsorption of Methylene Blue using the Biosorbent of Coconut Fiber Activated by Nitric Acid. Molekul 19. https://doi.org/10.29103/cejs.v2i2.7030 https://doi.org/10.20884/1.jm.2024.19.1.9443
Banamtuan, T.E., Baunsele, A.B., Kopon, A.M., 2023. Studi Adsorpsi Metilen Biru Memanfaatkan Sabut Buah Lontar. Jurnal Inovasi Teknik Kimia 8, 108–116. https://doi.org/10.31942/inteka.v8i2.8065
Desore, A., Narula, S.A., 2018. An overview on corporate response towards sustainability issues in textile industry. Environ Dev Sustain 20, 1439–1459. https://doi.org/10.1007/s10668-017-9949-1
Baunsele, A.B., Boelan, E.G., Kopon, A.M., Rahayu, R., Siswanta, D., 2022. Kinetic Study of Blue Methylene Adsorption Using Coconut Husk Base Activated. Indo. J. Chem. Res. 10, 110–116. https://doi.org/10.30598/ijcr.2022.10ans
Doğan-Sağlamtimur, N., Turaç, E., Arabacioğlu, R., Çivioğlu, T., 2017. Production of Dye from Green and Brown Walnut Shells for Leather Coloration. PEN 5. https://doi.org/10.21533/pen.v5i2.135
Etim, U.J., Umoren, S.A., Eduok, U.M., 2016. Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution. Journal of Saudi Chemical Society 20, S67–S76. https://doi.org/10.1016/j.jscs.2012.09.014
Baunsele, A.B., Boelan, E.G., Kopon, A.M., Taek, M.M., Tukan, G.D., Missa, H., 2023. Penggunaan Sabut Kelapa Teraktivasi NaOH sebagai Adsorben Metilen Biru: Utilization of Coconut Fiber NaOH-Activated as Blue Methylene Adsorbent. Kovalen 9, 43–54. https://doi.org/10.22487/kovalen.2023.v9.i1.16274
Firdaus Mohamad Yusop, M., Aziz, A., Azmier Ahmad, M., 2022. Conversion of teak wood waste into microwave-irradiated activated carbon for cationic methylene blue dye removal: Optimization and batch studies. Arabian Journal of Chemistry.
Baunsele, A.B., Kopon, A.M., Boelan, E.G., Leba, M.A.U., Taek, M.M., Tukan, G.D., Missa, H., Rahayu, 2024a. Pengaruh pH Dan Waktu Kontak Terhadap Adsorpsi Metilen Biru Menggunakan Serbuk Gergaji Kayu Jati. 15, 104081. https://doi.org/10.1016/j.arabjc.2022.104081
Alo 8, 1–11. https://doi.org/10.33369/alo.v8i1.32235
Baunsele, A.B., Missa, H., 2021. Langmuir and Freundlich Equation Test on Methylene Blue Adsorption by Using Hardian, A., Rosidah, R., Budiman, S., Syarif, D.G., 2021. Preparation of Composite Derived from Banana Peel Activated Carbon and MgFe₂O₄ as Magnetic Adsorbent for Methylene Blue Removal. J. Kim. Sains Apl. 23, 440–448. https://doi.org/10.14710/jksa.23.12.440-448
Aldosari, O.F., Jabli, M., Morad, M.H., 2023. Chemical extraction of cellulose from Ligno-cellulosic Astragalus armatus pods: Characterization, and application to the biosorption of methylene blue. Arabian Journal of Chemistry 16, 105019. https://doi.org/10.1016/j.arabjc.2023.105019
Al-Maliky, E.A., Gzar, H.A., Al-Azawy, M.G., 2021. Determination of Point of Zero Methylene Blue Adsorption. CHEESA 2, 42. https://doi.org/10.25273/cheesa.v2i1.4334
Oladoye, P.O., Ajiboye, T.O., Omotola, E.O., Oyewola, O.J., 2022. Methylene blue dye: Toxicity and potential elimination technology from wastewater. Results in Engineering.
Kumar, M., S., N, S., E, D., 2019. Photocatalytic Degradation of Methylene Blue Using Silver Nanoparticles Synthesized from Gymnema Sylvestre and Antimicrobial Assay. NRS 2. https://doi.org/10.31031/NRS.2019.02.000532
Pasang, P.M., Yunianta, Estiasih, T., Harijono, 2018. Structure And Morphology Of Cellulose From Coconut Coir Fibers. RJOAS 80, 452–462. https://doi.org/10.18551/rjoas.2018-08.61
Lellis, B., Fávaro-Polonio, C.Z., Pamphile, J.A., Polonio, J.C., 2019. Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnology Research and Innovation 3, 275–290. https://doi.org/10.1016/j.biori.2019.09.001
Qasem, N.A.A., Mohammed, R.H., Lawal, D.U., 2021. Removal of heavy metal ions from wastewater: a comprehensive and critical review. npj Clean Water 4, 36. https://doi.org/10.1038/s41545-021-00127-0
Mishra, Y., 2015. Adsorption Studies of Basic Dyes Onto Teak (Tectona Grandis) Leaf Powder. Journal of Urban and Environmental Engineering 9, 102–108. https://doi.org/10.4090/juee.2015.v9n2.102108
Riyanto, Mawazi, M., 2015. Electrochemical Degradation of Methylene Blue Using Carbon Composite Electrode (C-PVC) in Sodium Chloride. IOSR Journal of Applied Chemistry 8, 31–40. https://doi.org/10.9790/5736-081113140
Moniz, L., Tukan, M.B., Komisia, F., 2024. Optimasi Adsorpsi Metilen Biru Memanfaatkan Sabut Buah Lont